Homogeneous and Electrochemical Electron-Transfer Reaction of Nitrobenzene Anion Radical Dissolved in Nitrobenzene

Solvent free reaction of 1-chloro-2-nitrobenzene with anilines

An efficient solvent free reaction of 1-chloro-2-nitrobenzene with anilines to give N-substituted nitro anilines by nucleophilic aromatic substitution in good to excellent yields has been described. The effect of different salts on the reaction has also been studied.

Hydrogenation of Nitrobenzene to Aniline

Excited states in electron-transfer reaction products: ultrafast relaxation dynamics of an isolated acceptor radical anion.

The spectroscopy and ultrafast relaxation dynamics of excited states of the radical anion of a representative charge-transfer acceptor molecule, 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane, have been studied in the gas phase using time-resolved photoelectron spectroscopy. The photoelectron spectra reveal that at least two anion excited states are bound. Time-resolved studies show that ...

Doped liquid nitrobenzene is ferroelectric.

The high resolution hyper-Rayleigh light scattering spectrum for liquid nitrobenzene doped with triflic acid (CF(3)SO(3)H) shows a narrow spike at zero frequency shift which has the polarization signature of a polar longitudinal collective mode. This spectral spike disappears for pure nitrobenzene. The spectral spike is interpreted as due to ferroelectric domains in the liquid. The dopant molec...

Pressure and temperature studies of dielectric permittivity in the homogeneous phase of nitrobenzene–dodecane binary mixture

Ž . Ž . Results of isothermal high-pressure up to 120 MPa and isobaric Ps0.1 and 51 MPa temperature studies of dielectric Ž . Ž . permittivity in nitrobenzene–dodecane binary solution are presented. The dependencies of ́ P and ́ T obtained can be well portrayed by isomorphic relations with the same value of the critical exponent fs1yaf0.88. The influence of correction-to-scaling terms for the t...